Computational Structure Revision of a Longipinane Derivative Meridane

Publication Date

10-19-2016

Document Type

Article

Organizational Units

College of Natual Science and Mathematics, Chemistry and Biochemistry

Keywords

Longipinanes, Meridane, Structure revision

Abstract

Structure revision of a recently reported longipinane derivative, meridane, was enabled by computations of its NMR spectra. This structural revision necessitates corrections in the originally proposed Wagner–Meerwein mechanism for the formation of meridane.

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